Kali Linux Best — 32 Bit
You cannot pentest modern web apps without a modern browser. Firefox and Chromium still release 32-bit builds, but they are slow . Worse, many browser extensions (like Burp’s proxy companion or FoxyProxy) work fine, but the renderer will chug on modern JavaScript. Navigating a React-based admin panel on a 32-bit Kali VM is a lesson in patience.
But for real pentesting? Save yourself the headache. Go 64-bit. 32 bit kali linux
Use it to learn how operating systems work at a low level. Use it to practice buffer overflows (where 32-bit is actually easier than 64-bit). Use it to turn that e-waste into a dedicated wardriving box. You cannot pentest modern web apps without a modern browser